@article { ISI:000311056800010,
	title = {3D Hexaporous carbon assembled from single-layer graphene as high performance supercapacitor},
	journal = {Chemsuschem},
	volume = {5},
	number = {11},
	year = {2012},
	month = {OCT},
	pages = {2159-2164},
	publisher = {WILEY-V C H VERLAG GMBH},
	type = {Article},
	address = {BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY},
	keywords = {Electrochemistry, Energy storage, graphene, porous materials, Supercapacitors},
	issn = {1864-5631},
	doi = {10.1002/cssc.201200421},
	author = {Yadav, Prasad and Banerjee, Abhik and Unni, Sreekuttan and Jog, Jyoti Prakash and Kurungot, Sreekumar and Ogale, Satishchandra}
}
@article { ISI:000325548600016,
	title = {Redox-mediated synthesis of functionalised graphene: a strategy towards 2D multifunctional electrocatalysts for energy conversion applications},
	journal = {ChemPlusChem},
	volume = {78},
	number = {10},
	year = {2013},
	month = {OCT},
	pages = {1296-1303},
	publisher = {WILEY-V C H VERLAG GMBH},
	address = {BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY},
	abstract = {<p>A simple, one-step synthetic route for developing a two-dimensional multifunctional electrocatalyst is reported, by the functionalisation of graphene using oxidised ethylenedioxythiophene (O-EDOT). The mutually assisted redox reaction between graphene oxide (GO) and EDOT facilitates the reduction of GO to graphene with a concomitant deposition of O-EDOT on the surface of the graphene. The oxidised surface of GO catalyses the reaction without using an added reducing agent, so a controlled and uniform deposition of O-EDOT is ensured on the surface of graphene, which essentially prevents the restacking of the layers. UV/Visible, IR, Raman and X-ray photoelectron spectroscopy give valid evidence for the reduction and functionalisation of graphene sheets. The functional groups present on the surface of graphene are found to tune the physical and chemical properties of graphene. Consequently, the functionalised material displays enhanced electrocatalytic activity for the reduction of oxygen to water and I3- to I- relative to pristine graphene. These distinct property characteristics make the material a versatile cathode electrocatalyst for both alkaline anion-exchange membrane fuel cells and dye-sensitised solar cells.</p>},
	keywords = {electrocatalysts, fuel cells, graphene, redox chemistry, solar cells},
	issn = {2192-6506},
	doi = {10.1002/cplu.201300153},
	author = {Unni, SreeKuttan M. and Bhange, Siddheshwar N. and Anothumakkool, Bihag and Kurungot, Sreekumar}
}
@article {46766,
	title = {In situ preparation of ionomer as a tool for triple-phase boundary enhancement in 3D graphene supported Pt catalyst},
	journal = {Advanced Sustainable Systems},
	volume = {5},
	year = {2021},
	month = {JAN},
	pages = {2000125},
	type = {Article},
	abstract = {<p>For improving the performance of platinum electrocatalysts in polymer electrolyte membrane fuel cells (PEMFCs), it is important to enhance the Pt utilization level in the catalyst systems. A high performing electrocatalyst (Pt/3DNG) is developed for PEMFC applications by using nitrogen-doped 3D graphene (3DNG) as the support material and an in situ grafted active {\textquoteleft}{\textquoteleft}triple-phase boundary{\textquoteright}{\textquoteright} to more precisely control the formation of the proton conducting ionomer interface at the active sites. Considering the 3D morphology of the system, during the electrode fabrication for realistic single-cell evaluation, the concept of in situ generation of the proton conducting-ionomer based {\textquoteleft}{\textquoteleft}active triple-phase boundary{\textquoteright}{\textquoteright} is introduced, which could potentially replace the conventional method of using Nafion ionomer for the electrode preparation. The monomers owing to their small-size can access the pores and inner regions of the 3DNG support, which on UV-curing, undergo polymerization and transform into an ionomer with an extended interfacial network into the nanoregimes of 3DNG. Single cell evaluation of the membrane electrode assembly in a high-temperature PEMFC by using phosphoric acid doped polybenzimidazole membrane demonstrates the utility of the present strategy.</p>
},
	keywords = {electrocatalysts, fuel cells, graphene, oxygen reduction reaction},
	issn = {2366-7486},
	doi = {10.1002/adsu.202000125, Early Access Date = JUL 2020},
	author = {Gangadharan, Pranav K. and Vijayakumar, Vidyanand and Nediyirakkal, Shijil A. and Fernandez, Roshni Tresa and Siddharthan, V. Adhrika and Kurungot, Sreekumar}
}
