01814nas a2200217   4500008004100000022001400041245013900055210006900194260007700263300001400340490000700354520095800361653002601319653001101345653001401356653003901370653002101409100001701430700002001447856012901467       2013                        eng d  a1439-423500aPOM-catalyzed in situ ligand synthesis for the construction of metal complexes and their use in the formation of coordination polymers0 aPOMcatalyzed in situ ligand synthesis for the construction of me  aBOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANYbWILEY-V C H VERLAG GMBHcAPR  a1009-10150 v143 a<p>Six organicinorganic hybrid materials were synthesized by the in situ oxidation of neocuproine by using MoO3/Na2MoO4 as the catalyst in the presence of Cu(NO3)2. The crystal structures of Mo8-Cu4-PHEN and Mo8-Cu2-5(2PIC) are composed of [Mo8O26]4 polyoxometalate (POM) units, whereas the crystal structure of Mo6-Cu-COPHEN is composed of a [Mo6O19]2 POM unit; both POM units could be considered as the active form of the catalyst. Reaction of the hybrid materials with 1,3,5-benzenetricarboxylic acid (BTC) resulted in the formation of two different coordination polymers (CPs) under different reaction conditions. These CPs, depending on their structural attributes, exhibit distinct differences in the adsorption of H2, CO2, and water. The use of 2-methylpyridine instead of neocuproine does not give any oxidation products under the same reaction conditions due to the incorrect positioning of the methyl group with respect to the CuII center.</p>10acoordination polymers10aCopper10aN ligands10aorganicinorganic hybrid composites10apolyoxometalates1 aDey, Chandan1 aBanerjee, Rahul  uhttp://library.ncl.res.in/content/pom-catalyzed-situ-ligand-synthesis-construction-metal-complexes-and-their-use-formation-001461nas a2200193   4500008004100000022001400041245007300055210006900128260000800197490000700205520082600212653002501038653002101063653002201084653002101106653002101127100001701148856010201165       2022                        eng d  a1040-727800aPolyoxometalate clusters: inorganic ligands for functional materials0 aPolyoxometalate clusters inorganic ligands for functional materi  cSEP0 v333 a<p>
	Research in polyoxometalates (POMs) is a diverse growing field with variations in application. POMs are consisting of metal ion and oxide. Peripheral oxides of POM can share spare electron pairs to behave as ligands. This property of POM was utilized for constructing coordination polymers (CPs), synthesizing transitional metal substituted POM for catalysis, synthesizing and stabilizing nano-particles, etc. POM connected structures have provided an opportunity of heterogenization of some homogeneous POM catalyst. Furthermore, diamagnetic POM ligands have been suitable for stabilizing and isolating magnetic ions inside clusters. The scope of this review is to summarize the role of POMs as ligands to prepare POM based CPs, synthesize and stabilize metal nano-particles and isolate magnetic ion or unit.</p>
10aCoordination polymer10aInorganic ligand10amaterials science10apolyoxometalates10asynthesis design1 aDey, Chandan  uhttp://library.ncl.res.in/content/polyoxometalate-clusters-inorganic-ligands-functional-materials